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I have worked extensively on convergent margin volcanism (in Indonesia,
the Andes, and the Lesser Antilles) with particular emphasis on the nature
of the subducting slab and the provenance of volatiles from arc-related
volcanoes. Initial work in Indonesia (with Harmon Craig) showed the spectacular
sensitivity of helium isotopes to the mapping of compositional changes
in the subducting slab - from oceanic to continental margin affinity -
at the juncture of the Sunda and Banda arcs. This was followed-up by a
study directed at explaining the apparent 'decoupling' of helium and strontium
isotopes across this particular region, and pinpointing subducted continental
margin and not subducted sediments as the source of the radiogenic helium
emitted along the arc. Further studies in Indonesia have considered the
problems of distinguishing 'crustal' signatures from the slab versus upper-level
contamination effects (a topic clearly of relevance to the debate over
Heard Island and low-3He hotspots).
Research projects in the Andes and Lesser Antilles were undertaken specifically
to consider the respective effects of thickened crust and sediment variations
on the volatile characteristics of convergent margin volcanism.
It was concluded that eruption of magmas through thickened continental crust
could have a major effect on the volatile systematics, and that in many
instances helium could trace the effects of assimilation/contamination
processes far more sensitively than other geochemical indicators. Current
work in the Lesser Antilles is aimed at evaluating the effects of changes
in sediment composition (on the down-going slab) on the CO2 flux of arc
volcanoes. The theme common to both studies is understanding the volatile
mass balance of the subduction process.
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